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Pure Appl. Chem. 75(9), 1207-1210, 2003

Pure and Applied Chemistry

Vol. 75, Issue 9

Rearrangements in the nona-and azanonaborane clusters*

M. El-Zaria, U. Dörfler, and D. Gabel

Department of Chemistry, University of Bremen, D-28334 Bremen, Germany

Abstract: In the conversion of nonaboranes B9H13SMe2 to azanonaboranes B8NH11-NHR, one boron atom is lost. This boron atom was identified, and a pathway for the rearrangement of the cluster is proposed, based on the fate of covalently labeled boron atoms.

*Lecture presented at the XIth International Meeting on Boron Chemistry (IMEBORON XI), Moscow, Russia, 28 July - 2 August 2002. Other presentations are published in this issue, pp. 1157-1355.


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