Synthetic applications of planar chiral cationic η³-allylmolybdenum
complexes
P. Kocienski, R. Bell, E. Bourque, J. A. Christopher, J. Cooksey, A.
Gunn, A. Kuhl, Y. Li, S. Uppal, and J. Yuen
Department of Chemistry, Leeds University, Leeds LS2
9JT, UK; Department of Chemistry, Glasgow University, Glasgow G12 8QQ,
UK; GlaxoSmithKline Research and Development, Medicines Research Centre,
Stevenage, Hertfordshire SG1 2NY, UK
Abstract: The synthesis of planar chiral η³-allylmolybdenum
complexes is described together with some examples of the nucleophilic
addition of organocopper(I) reagents.
*Plenary and invited lectures presented at the 12th
International Symposium on Organometallic Chemistry Directed Towards
Organic Synthesis (OMCOS-12), Toronto, Ontario, Canada, 6-10 July 2003.
Other lectures are published in this issue, pp.
453-695.
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