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Pure Appl.
Chem., Vol. 70, No. 4, pp. 993-1014, 1998
ANALYTICAL CHEMISTRY
DIVISION
COMMISSION ON GENERAL ASPECTS OF ANALYTICAL CHEMISTRY
Guidelines for Calibration in Analytical
Chemistry Part 1: Fundamentals and Single Component Calibration
(IUPAC Recommendation 1998)
K. Danzer and
L. A. Currie
Synopsis: This IUPAC nomenclature document has been prepared
to establish a uniform and meaningful approach to terminology, notation,
and formulation for calibration in analytical chemistry. In this first
part, general fundamentals of calibration are presented, namely for
both relationships of qualitative and quantitative variables (relations
between variables characterizing certain types of analytes and measured
signals in certain positions of a measured function on the one hand
and between variables characterizing the amount or concentration of
the chemical species and the intensities of the measured signals, on
the other hand). On this basis, the fundamentals of the common single
component calibration which models the relationships y = f(x)
between the signal intensities y and the amounts or concentration
are represented. Additional papers will be prepared dealing with extensive
relationships between several signal intensities and analyte contents,
namely with multivariate calibration and with optimization and experimental
design.
> full
text - pdf 1.06MB
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